秋季渤海和北黄海海水中挥发性卤代烃的分布与通量

doi:10.13634/j.cnki.mes20150401

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摘要使用吹扫-捕集气相色谱法于2013年11月对渤海和北黄海海水中4种常见的挥发性卤代烃(VHCs)浓度进行了分析。结果表明:秋季渤海和北黄海表层海水中CHBr₂Cl、CHBr₃、C₂HCl₃和C₂Cl₄的浓度平均值和变化范围分别为7.03(4.23~12.63) pmol/L、19.61(5.99~55.00) pmol/L、20.37(1.68~58.25) pmol/L和41.03(10.84~96.94)pmol/L。受生物生产、人为输入、陆地径流等因素的共同作用,4种VHCs浓度呈现出不同的空间分布特征,总体表现为渤海海域由北向南递减,北黄海海域山东半岛以北、鸭绿江口浓度较低的特点。受地理位置和水文条件的影响,不同站位VHCs浓度在垂直分布上有较大差异,但最大值均出现在真光层。周日变化研究表明:VHCs在13:00和17:00浓度较大,7:00和21:00浓度较低,说明VHCs生产释放受光照和潮汐等因素的共同影响。采用Liss和Salter双膜模型估算了CHBr₂Cl、CHBr₃、C₂HCl₃和C₂Cl₄的海-气通量,结果分别为36.28(0.13~109.54)nmol/m²·d、85.96(-8.9~308.61)nmol/m²·d、191.71(0.10~386.67)nmol/m²·d和285.14(0.19~914.85)nmol/m²·d,表明在调查期间渤海和北黄海是大气中CHBr₂Cl、CHBr₃、C₂HCl₃和C₂Cl₄的源。

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	柳秋林
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关键词：挥发性卤代烃渤海北黄海浓度分布周日变化海-气通量

Abstract：Volatile halocarbons (VHCs) are important atmospheric trace gases,which play significant roles in the global warming and atmospheric chemistry.The concentrations of four VHCs in the Bohai Sea (BS) and northern Yellow Sea (NYS) were measured.The results showed that the concentrations of CHBr₂Cl,CHBr₃,C₂HCl₃ and C₂Cl₄in the surface seawater of the BS and NYS were 7.03 (4.23~12.63) pmol/L,19.61 (5.99~55.00) pmol/L,20.37 (1.68~58.25) pmol/L,41.03 (10.84~96.94) pmol/L,respectively.The distributions of the four VHCs in the surface water of the BS and NYS were clearly influenced by the combined actions of biological production,anthropogenic activities and riverine input,and exhibited a gradually decreasing trend from north to south in the BS,with the minimum concentrations appearing on the north of Shandong Peninsula and in the Yalu River estuary.The depth profiles of the four VHCs were characterized by the maxima in the euphotic layer due to the impacts of geographical locations and hydrological conditions.The diel variation of VHCs was investigated at a fixed station.The results showed that the lowest concentrations of the four VHCs occurred at 7:00 and 21:00,while the highest values appeared at 13:00 and 17:00,indicating that a combination of illumination and tide might be responsible for the diurnal variation of VHCs.On the basis of gas exchange model and surface concentrations of VHCs,the mean sea-to-air fluxes of four VHCs in the study area were estimated to be 36.28 (0.13~109.54) nmol/m²·d,85.96 (-8.9~308.61) nmol/m²·d,191.71 (0.10~386.67) nmol/m²·d,285.14 (0.19~914.85) nmol/m²·d,respectively,indicating that the investigated area appeared to be a source of atmospheric CHBr₂Cl,CHBr₃,C₂HCl₃ and C₂Cl₄ during the study time.

Key words： volatile halocarbons distribution diurnal variation Bohai Sea northern Yellow Sea sea-to-air flux

收稿日期: 2014-07-08;

PACS:

基金资助:

国家自然科学基金重大国际合作项目(41320104008);教育部"长江学者"奖励计划项目;山东省"泰山学者"建设工程项目

通讯作者: 杨桂朋,E-mail:gpyang@mail.ouc.edu.cn E-mail: gpyang@mail.ouc.edu.cn

作者简介:柳秋林(1989-),男,山东青岛人,硕士研究生,主要研究方向为海洋生源活性气体,E-mail:liuqiulin.love@163.com

引用本文:

柳秋林,何真,杨桂朋. 秋季渤海和北黄海海水中挥发性卤代烃的分布与通量[J]. 海洋环境科学, 2015, 34(4): 481-487.

LIU Qiu-lin,HE Zhen,YANG Gui-peng. Distributions and sea-to-Air fluxes of volatile halocarbons in the Bohai Sea and northern Yellow Sea[J]. Marine Environmental Science, 2015, 34(4): 481-487.

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http://hyhjkx.nmemc.org.cn/CN/10.13634/j.cnki.mes20150401 或 http://hyhjkx.nmemc.org.cn/CN/Y2015/V34/I4/481

References

[1]	杨桂朋,尹士序,陆小兰,等.吹扫-捕集气相色谱法测定海水中挥发性卤代烃[J].中国海洋大学学报:自然科学版,2007,37(2):299-304.
[2]	SOLOMON S.Progress towards a quantitative understanding of Antarctic ozone depletion[J].Nature,1990,347(6291):347-354.
[3]	MOORE R M,GROSZKO W,NIVEN S J.Ocean-atmosphere exchange of methyl chloride:results from NW Atlantic and Pacific Ocean studies[J].Journal of Geophysical Research:Oceans (1978-2012),1996,101(C12):28529-28538.
[4]	JEFFREY S W,MANTOURA R F C,WRIGHT S W.Phytoplankton pigments in oceanography:guidelines to modern methods[M].Paris:UNESCO,1997.
[5]	于非,张志欣,刁新源,等.黄海冷水团演变过程及其与邻近水团关系的分析[J].海洋学报,2006,28(5):26-34.
[6]	沈志良,陆家平,刘兴俊,等.长江口区营养盐的分布特征及三峡工程对其影响[J].海洋科学集刊,1992,33:107-129.
[7]	SOLOMON S,Mills M,Heidt L E,et al.On the evaluation of ozone depletion potentials[J].Journal of Geophysical Research:Atmospheres (1984-2012),1992,97(D1):825-842.
[8]	NIGHTINGALE P D,MALIN G,LISS P S.Production of chloroform and other low molecular-weight halocarbons by some species of macroalgae[J].Limnology and Oceanography,1995,40(4):680-689.
[9]	REIFENHÄUSER W, HEUMANN K G.Bromo- and bromochloromethanes in the Antarctic atmosphere and the South Polar Sea[J].Chemosphere,1992,24(9):1293-1300.
[10]	CARPENTER L J,LISS P S.On temperate sources of bromoform and other reactive organic bromine gases[J].Journal of Geophysical Research:Atmospheres (1984-2012),2000,105(D16):20539-20547.
[11]	REIFENHÄUSER W,HEUMANN K G.Determinations of methyl iodide in the Antarctic atmosphere and the South Polar Sea[J].Atmospheric Environment.Part A.General Topics,1992,26(16):2905-2912.
[12]	MOORE R M,WEBB M,TOKARCZYK R,et al.Bromoperoxidase and iodoperoxidase enzymes and production of halogenated methanes in marine diatom cultures[J].Journal of Geophysical Research:Oceans (1978-2012),1996,101(C9):20899-20908.
[13]	杨桂朋,张亮,陆小兰,等.黄海海水微表层和次表层中挥发性卤代烃的浓度和分布[J].中国海洋大学学报:自然科学版,2009,39(5):1077-1086.
[14]	杨桂朋,尹士序,陆小兰,等.吹扫-捕集气相色谱法测定海水中挥发性卤代烃[J].中国海洋大学学报:自然科学版,2007,37(2):299-304.
[15]	CHUCK A L,TURNER S M,LISS P S.Oceanic distributions and air-sea fluxes of biogenic halocarbons in the open ocean[J].Journal of Geophysical Research:Oceans (1978-2012),2005,110(10):C10022,doi:10.1029/2004JC002741.
[16]	MOORE R M,GROSZKO W,NIVEN S J.Ocean-atmosphere exchange of methyl chloride:results from NW Atlantic and Pacific Ocean studies[J].Journal of Geophysical Research:Oceans (1978-2012),1996,101(C12):28529-28538.
[17]	JEFFREY S W,MANTOURA R F C,WRIGHT S W.Phytoplankton pigments in oceanography:guidelines to modern methods[M].Paris:UNESCO,1997.
[18]	于非,张志欣,刁新源,等.黄海冷水团演变过程及其与邻近水团关系的分析[J].海洋学报,2006,28(5):26-34.
[19]	沈志良,陆家平,刘兴俊,等.长江口区营养盐的分布特征及三峡工程对其影响[J].海洋科学集刊,1992,33:107-129.
[20]	ABRAHAMSSON K,EKDAHL A,COLLÉN J,et al.Marine algae-a source of trichloroethylene and perchloroethylene[J].Limnology and Oceanography,1995,40(7):1321-1326.
[21]	江蓓洁,鲍献文,吴德星,等.北黄海冷水团温、盐多年变化特征及影响因素[J].海洋学报,2007,29(4):1-10.
[22]	NIGHTINGALE P D,MALIN G,LISS P S.Production of chloroform and other low molecular-weight halocarbons by some species of macroalgae[J].Limnology and Oceanography,1995,40(4):680-689.
[23]	KHALIL M A K,MOORE R M,HARPER D B,et al.Natural emissions of chlorine-containing gases:Reactive Chlorine Emissions Inventory[J].Journal of Geophysical Research:Atmospheres (1984-2012),1999,104(D7):8333-8346.
[24]	CARPENTER L J,LISS P S.On temperate sources of bromoform and other reactive organic bromine gases[J].Journal of Geophysical Research:Atmospheres (1984-2012),2000,105(D16):20539-20547.
[25]	EKDAHL A,PEDERSÉN M,ABRAHAMSSON K.A study of the diurnal variation of biogenic volatile halocarbons[J].Marine Chemistry,1998,63(1/2):1-8.
[26]	MOORE R M,WEBB M,TOKARCZYK R,et al.Bromoperoxidase and iodoperoxidase enzymes and production of halogenated methanes in marine diatom cultures[J].Journal of Geophysical Research:Oceans (1978-2012),1996,101(C9):20899-20908.
[27]	杨桂朋,张亮,陆小兰,等.黄海海水微表层和次表层中挥发性卤代烃的浓度和分布[J].中国海洋大学学报:自然科学版,2009,39(5):1077-1086.
[28]	ABRAHAMSSON K,LORÉN A,WULFF A,et al.Air-sea exchange of halocarbons:the influence of diurnal and regional variations and distribution of pigments[J].Deep Sea Research Part II:Topical Studies in Oceanography,2004,51(22/23/24):2789-2805.
[29]	白凤龙,高建华,汪亚平,等.鸭绿江口的潮汐特征[J].海洋通报,2008,27(3):7-13.
[30]	CHUCK A L,TURNER S M,LISS P S.Oceanic distributions and air-sea fluxes of biogenic halocarbons in the open ocean[J].Journal of Geophysical Research:Oceans (1978-2012),2005,110(10):C10022,doi:10.1029/2004JC002741.
[31]	LISS P S,SLATER P G.Flux of gases across the air-sea interface[J].Nature,1974,247(5438):181-184.
[32]	LISS P S,MERLIVAT L.Air-sea gas exchange rates:Introduction and synthesis[M]//BUAT-MÉNARD P.The role of air-sea exchange in geochemical cycling.Netherlands:Springer,1986:113-127.
[33]	ABRAHAMSSON K,EKDAHL A,COLLÉN J,et al.Marine algae-a source of trichloroethylene and perchloroethylene[J].Limnology and Oceanography,1995,40(7):1321-1326.
[34]	江蓓洁,鲍献文,吴德星,等.北黄海冷水团温、盐多年变化特征及影响因素[J].海洋学报,2007,29(4):1-10.
[35]	MOORE R M.The solubility of a suite of low molecular weight organochlorine compounds in seawater and implications for estimating the marine source of methyl chloride to the atmosphere[J].Chemosphere - Global Change Science,2000,2(1):95-99.
[36]	KHALIL M A K,MOORE R M,HARPER D B,et al.Natural emissions of chlorine-containing gases:Reactive Chlorine Emissions Inventory[J].Journal of Geophysical Research:Atmospheres (1984-2012),1999,104(D7):8333-8346.
[37]	ZHOU Y,VARNER R K,RUSSO R S,et al.Coastal water source of short-lived halocarbons in New England[J].Journal of Geophysical Research:Atmospheres (1984-2012),2005,110(D21); D21302,doi:10.1029/2004JD005603.
[38]	EKDAHL A,PEDERSÉN M,ABRAHAMSSON K.A study of the diurnal variation of biogenic volatile halocarbons[J].Marine Chemistry,1998,63(1/2):1-8.
[39]	CARPENTER L J,LISS P S,PENKETT S A.Marine organohalogens in the atmosphere over the Atlantic and Southern Oceans[J].Journal of Geophysical Research:Atmospheres (1984-2012),2003,108(D9):4256,doi:10.1029/2002JD002769.
[40]	ABRAHAMSSON K,LORÉN A,WULFF A,et al.Air-sea exchange of halocarbons:the influence of diurnal and regional variations and distribution of pigments[J].Deep Sea Research Part II:Topical Studies in Oceanography,2004,51(22/23/24):2789-2805.
[41]	白凤龙,高建华,汪亚平,等.鸭绿江口的潮汐特征[J].海洋通报,2008,27(3):7-13.
[42]	SCHALL C,HEUMANN K G.GC determination of volatile organoiodine and organobromine compounds in arctic seawater and air samples[J].Fresenius' Journal of Analytical Chemistry,1993,346(6/7/8/9):717-722.
[43]	LISS P S,SLATER P G.Flux of gases across the air-sea interface[J].Nature,1974,247(5438):181-184.
[44]	LISS P S,MERLIVAT L.Air-sea gas exchange rates:Introduction and synthesis[M]//BUAT-MÉNARD P.The role of air-sea exchange in geochemical cycling.Netherlands:Springer,1986:113-127.
[45]	RIVETT A C,MARTIN D,NICKLESS G,et al.In situ gas chromatographic measurements of halocarbons in an urban environment[J].Atmospheric Environment,2003,37(16):2221-2235.