中国近海大气有机氮干沉降通量的时空变化特征

Characteristics of atmospheric dry deposition of organic nitrogen over China Seas

  • 摘要: 有机氮对大气氮循环及海洋生态系统具有重要意义。本研究利用空气质量模型WRF-CMAQ分析了2013年和2017年夏季、冬季中国近海大气有机氮干沉降通量时空变化特征,探究了海盐非均相反应对有机氮干沉降通量的影响及光化学污染期间有机氮干沉降通量变化特征。结果表明:2013年、2017年中国近海大气有机氮干沉降量为0.06~0.25 mg N/(m2·d),夏季有机氮干沉降通量由北向南逐渐减少渤海0.15 mg N/(m2·d)、黄海0.09 mg N/(m2·d)、东海0.06 mg N /(m2·d);冬季则相反,东海最高0.22 mg N /(m2·d),渤海最低0.05 mg N/(m2·d)。2013年到2017年,渤海和黄海近岸海域有机氮干沉降通量增加(12%~17%),其余海域降低(4%~35%)。光化学污染期间,大气有机氮干沉降通量增大(3.1~3.5倍)。海盐非均相反应使部分海域有机氮干沉降通量增加4.2~9.2 μg N/(m2·d)(10%~40%)。

     

    Abstract: Organic nitrogen is a crucial component of atmospheric nitrogen compounds, playing a significant role in the nitrogen cycle and marine ecosystems. This study utilized the third-generation air quality model WRF-CMAQ to estimate the dry deposition flux of atmospheric organic nitrogen over the China offshore regions during summer and winter in 2013 and 2017. We analyzed the spatiotemporal variations, quantified the impact of sea salt heterogeneous reactions on the deposition flux of atmospheric organic nitrogen to the ocean, and explored the changes in deposition flux characteristics during photochemical pollution events. The results indicate that the average dry deposition flux of atmospheric organic nitrogen over the China offshore regions in 2013 and 2017 ranged from 0.06 to 0.25 mg N/(m2·d). During summer, the deposition flux gradually decreased from north to south Bohai Sea: 0.15 mg N/(m2·d), Yellow Sea: 0.09 mg N/(m2·d), East China Sea: 0.06 mg N/(m2·d), while the opposite trend was observed during winter, with the highest flux in the East China Sea 0.22 mg N /(m2·d)/(m2·d)and the lowest in the Bohai Sea 0.05 mg N/(m2·d). From 2013 to 2017, the deposition flux of organic nitrogen increased in the Bohai Sea and the western coastal areas of the Yellow Sea (12%-17%), while decreasing in other areas (4% - 35%). During photochemical pollution events, the deposition flux of atmospheric organic nitrogen significantly increased (3.1-3.5 times). Sea salt surface heterogeneous reactions could enhance the deposition flux of organic nitrogen by 4.2-9.2 μg N/(m2·d)(10% - 40%) in certain regions, with a higher impact during winter than summer.

     

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