用于海上油气田生产水在线监测的水中油近紫外与深紫外传感器比较研究

Comparative study of near and far-ultraviolet sensors for oil-in-water online monitoring of offshore platform produced water

  • 摘要: 海洋石油平台生产水排放对海洋环境产生一定的污染,目前主要采用人工取样化验的手段来进行监测,缺少适用于海上油气田生产水中含油浓度的水中油在线监测技术。本文以海洋石油平台生产水为研究对象,选取近紫外和深紫外两种不同激发波长的水中油传感器测试不同油田区域的含油水样,建立荧光信号与含油浓度之间的相关关系,并从紫外荧光法测量原理出发,研究4个海上油田区域的含油水样荧光光谱特性。实验证明,激发波长为360 nm的近紫外水中油传感器可应用于轻质油到重质油等不同密度油品生产水的水中油浓度检测,但对低浓度检测的敏感度低;激发波长为255 nm的深紫外水中油传感器在除重质油外的其他油田生产水检测中较为理想,但是在浓度较高区域易过早产生荧光猝灭,因此,应综合考虑油品类型及日常检测浓度范围选择海上石油平台生产水在线监测的水中油传感器波长。本文结果可为海上溢油的石油类快速检测提供参考。

     

    Abstract: The discharge of produced water from offshore oil platform is one of the important sources of marine environmental pollution. While manual sampling and analysis are still the main methods,it is urgent to study the online monitoring technology of oil in water for production water of offshore oil platform. In this paper, oil-bearing produced water samples from different offshore oilfields were taken as the research object, and were tested by both near-ultraviolet and deep ultraviolet oil sensors with different excitation wavelengths. The fluorescence spectral characteristics of oily water samples were studied and the correlation between fluorescence signal and oil content was established. The near-ultraviolet oil sensor with an excitation wavelength of 360 nm can be applied to detect oil concentration in produced water with density range from light oil to heavy oil, but the sensitivity to low concentration is low; The deep ultraviolet oil sensor with an excitation wavelength of 255 nm is ideal for produced water from non-heavy oil oilfields except heavy oil, and fluorescence quenching is easy to occur prematurely in higher concentrations. As a result, the oil type and daily detection concentration range should be comprehensively considered to select the wavelength of the oil sensor for online monitoring of produced water in offshore platforms. The outcomes of this paper can provide a reference for the rapid detection of oil spills at sea.

     

/

返回文章
返回