Abstract：Chloral represents one kind of common non-volatile chlorination by-product of the drained concentrated seawater from a seawater desalination plant, which has been proved to have mutagenicity.Therefore, it is necessary to establish a fast, sensitive and accurate method for detecting the concentration of chloral in concentrated seawater.Herein, a method is developed for this purpose by headspace and capillary GC with an electron capture detector(μECD).Determination parameters, such as headspace time, headspace temperature and seawater salinity are discussed in detail.The detection limits and correlation coefficient of method are respectively 0.006 μg/L and 0.9996.This method can be employed in the chloral concentration range of 0.05~20.0 μg/L.The relative standard deviation (RSD) is 0.51%~1.9%.Additionally, test for recovery is made by standard addition method, giving results in the range of 96.1%~113.9%.
LIU Jing,ZENG Xing-yu,ZHOU Dong-xing. Determination of chloral in seawater by headspace and gas chromatography[J]. Marine Environmental Science, 2016, 35(3): 434-437.
IPCC.Climate Change 2007:The physical science basis[M]//SOLOMON S,QIN D,MANNING M,et al.Contribution of Working Group I to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change.Cambridge:Cambridge University Press,2007:996.
[2]
PROBYN T A,BERNARD S,PITCHER G C,et al.Ecophysiological studies on Aureococcus anophagefferens blooms in Saldanha Bay,South Africa[J].Harmful Algae,2010,9(2):123-133.
[3]
河北省海洋局.2009年河北省海洋环境质量公报[R].石家庄:河北省海洋局,2010.
[4]
河北省海洋局.2010年河北省海洋环境状况公报[R].石家庄:河北省海洋局,2011.
[5]
河北省海洋局.2011年河北省海洋环境状况公报[R].石家庄:河北省海洋局,2012.
[6]
河北省海洋局.2012年河北省海洋环境状况公报[R].石家庄:河北省海洋局,2013.
[7]
河北省海洋局.2013年河北省海洋环境状况公报[R].石家庄:河北省海洋局,2014.
[8]
河北省海洋局.2014年河北省海洋环境状况公报[R].石家庄:河北省海洋局,2015.
[9]
YU J Y,KAO H Y,LEE T.Subtropics-related interannual sea surface temperature variability in the central equatorial pacific[J].Journal of Climate,2010,23(11):2869-2884.
[10]
PIOCH S,SAUSSOLA P,KILFOYLEB K,et al.Ecological design of marine construction for socio-economic benefits:ecosystem integration of a pipeline in coral reef area[J].Procedia Environmental Sciences,2011,9:148-152.
[11]
PORZIO L,BUIA M C,HALL-SPENCER J M.Effects of ocean acidification on macroalgal communities[J].Journal of Experimental Marine Biology and Ecology,2011,400(1/2):278-287.
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